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LEADER: 03735nam a22004935a 4500
001 013923387-3
005 20140314191255.0
008 140121s2014 gw | s ||0| 0|eng d
020 $a9783642403675
020 $a9783642403675
020 $a9783642403668
024 7 $a10.1007/978-3-642-40367-5$2doi
035 $a(Springer)9783642403675
040 $aSpringer
050 4 $aTA1750-1750.22
072 7 $aTJFD$2bicssc
072 7 $aTEC021000$2bisacsh
072 7 $aTEC008080$2bisacsh
082 04 $a620.11295$223
082 04 $a620.11297$223
100 1 $aManjon, Francisco Javier,$eeditor.
245 10 $aPressure-Induced Phase Transitions in AB2X4 Chalcogenide Compounds /$cedited by Francisco Javier Manjon, Ion Tiginyanu, Veaceslav Ursaki.
264 1 $aBerlin, Heidelberg :$bSpringer Berlin Heidelberg :$bImprint: Springer,$c2014.
300 $aXIII, 243 p. 121 illus., 33 illus. in color.$bonline resource.
336 $atext$btxt$2rdacontent
337 $acomputer$bc$2rdamedia
338 $aonline resource$bcr$2rdacarrier
347 $atext file$bPDF$2rda
490 1 $aSpringer Series in Materials Science,$x0933-033X ;$v189
505 0 $aIntroduction -- Part I Spinel-Structured AB Chalcogenide Compounds -- Part II Ordered-Vacancy AB Chalcogenide Compounds -- Part III Chalcogenide Compounds with other Types of Structures.
520 $aThis book on pressure-induced phase transitions in AB2X4 chalcogenide compounds deals with one important AmBnXp material. The interest in these materials is caused by their properties. The results are discussed for three main groups of structural families: cubic-spinel structures, defective tetragonal structures, and other structures like layered and wurtzite-type modifications. A systematic analysis of the behavior of cubic (spinel), tetragonal (defect chalcopyrites and stannites) and other crystal modifications of AB2X4 compounds under hydrostatic pressure is performed. The behavior of AIIAl2S4, AIIGa2S4, AIIAl2Se4 and AIIGa2Se4 compounds with defective tetragonal structures, compounds with layered and wurtzite structures under hydrostatic pressure and the pressure dependence of the band gap, lattice parameters, interatomic distances, vibrational modes and pressure-induced phase transitions is discussed. Many of these compounds, except oxide spinels, undergo a pressure-induced phase transition towards the rocksalt-type structure. The phase transition is preceded by disorder in the cation sublattice. The dependence of the transition pressure to the rocksalt-type structure as a function of the compound ionicity and the size criterion is analyzed. At high pressures, all ordered-vacancy compounds are found to exhibit a band anticrossing between several conduction bands that leads to a strong decrease of its pressure coefficient and consequently to a strong non-linear pressure dependence of the direct bandgap energy. Theoretical studies of phase transitions in several ordered-vacancy compounds reveal that the existence of ordered vacancies alter the cation-anion bond distances and their compressibilities. The book is written for students, Ph D. students and specialists in materials science, phase transitions and new materials.
650 20 $aSemiconductors.
650 10 $aMaterials science.
650 0 $aMicrowaves.
650 0 $aOptical materials.
650 24 $aOptical and Electronic Materials.
650 24 $aMicrowaves, RF and Optical Engineering.
650 24 $aApplied and Technical Physics.
700 1 $aUrsaki, Veaceslav,$eeditor.
700 1 $aTiginyanu, Ion,$eeditor.
776 08 $iPrinted edition:$z9783642403668
830 0 $aSpringer Series in Materials Science ;$v189.
988 $a20140204
906 $0VEN