Record ID | ia:biocatalystsinor0000halg |
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008 920306s1992 ne a b 001 0 eng
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050 00 $aQD262$b.H248 1992
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100 1 $aHalgas , Ja n.
245 10 $aBiocatalysts in organic synthesis /$cJa n Halgas .
260 $aAmsterdam ;$aNew York :$bElsevier,$c1992.
300 $axiv, 334 pages :$billustrations ;$c24 cm.
336 $atext$btxt$2rdacontent
337 $aunmediated$bn$2rdamedia
338 $avolume$bnc$2rdacarrier
490 1 $aStudies in organic chemistry ;$v46
504 $aIncludes bibliographical references (pages 301-324) and index.
505 0 $a1. Enzymes -- Catalysts of Life. 1.1. Classification of enzymes. 1.2. Principles of the kinetics of enzymatic reactions. 1.2.1. Inhibitors, inhibition with substrate and product. 1.3. Effects of organic solvents on enzymes. 1.4. Effects of temperature and pH on the stability and activity of enzymes. 1.5. Units of enzymatic activity -- 2. The Biocatalyst Form. 2.1. Free enzymes. 2.1.1. Characteristics of free enzymes. 2.1.2. Modified enzymes. 2.2. Immobilized enzymes. 2.2.1. Methods of the enzyme immobilization. 2.2.2. Properties of immobilized enzymes. 2.3. Cells of microorganisms. 2.3.1. Transformations by growing cells. 2.3.2. Transformations by preliminarily grown cells. 2.4. Immobilized cells of microorganisms. 2.4.1. Methods of cell immobilization. 2.4.2. Simultaneous immobilization of several biocatalysts. 2.5. Plant and animal cells. 2.6. Non-enzymatic biopreparations -- 3. Biocatalysts and the Problem of Selectivity in Organic Synthesis. 3.1. Specificity of chemical action and substrate specificity of enzymes. 3.2. Differentiation of enantiomers. 3.3. Differentiation of enantiotopic groups. 3.4. Differentiation of enantiotopic sides -- 4. Substitution Reactions Using Biocatalysts. 4.1. Methylations. 4.2. Halogenations. 4.3. Substitution reactions in the side chain of amino acids. 4.4. Substitutions on aromatic systems with the formation of a C=C bond. 4.5. Substitutions at C-1 in saccharides -- 5. Elimination and Addition Reactions. 5.1. Additions to the C=C bond. 5.2. Additions to the C=O bond -- 6. Syntheses and Hydrolyses of Esters. 6.1. Syntheses of esters. 6.2. Chemo- and regioselective hydrolyses of esters. 6.3. Kinetic resolutions of racemic esters, acids and alcohols. 6.3.1. Hydrolysis and transesterification of esters of racemic acids. 6.3.2. Resolution of racemic alcohols through esters. 6.4. Diesters of prochiral dicarboxylic acids. 6.5. Prochiral diols -- 7. Syntheses and Hydrolyses of Amides. 7.1. Syntheses of amides and peptides. 7.2. Hydrolyses of amides and nitriles -- 8. Oxidations. 8.1. Oxidation of alcohols. 8.2. Further oxidation reactions. 8.2.1. The Baeyer-Villiger oxidation. 8.2.2. Hydroxylations. 8.2.3. Dehydrogenations of the CH-CH bond. 8.2.4. Oxidations of amino acids to oxo acids. 8.2.5. Oxidations of nitrogenous heterocyclic compounds. 8.2.6. Oxidations on nitrogen, sulphur or selenium atoms -- 9. Reductions. 9.1. Reductions of aldehydes and acyclic ketones. 9.2. Reductions of cyclic ketones. 9.3. Reductions of di- and tricarbonyl compounds. 9.4. Reductions of oxo acids, oxo esters and oxo amides. 9.5. Reductions of the carbonyl group in organometallic compounds. 9.6. Reductions of the C=C bond. 9.7. Syntheses of [alpha]-amino acids from [alpha]-oxo acids. 9.8. Reductions of the nitro group. 9.9. Miscellaneous reductions.
650 0 $aOrganic compounds$xSynthesis.
650 0 $aEnzymes.
650 1 $aEnzymes.
650 7 $aEnzymes.$2fast$0(OCoLC)fst00913605
650 7 $aOrganic compounds$xSynthesis.$2fast$0(OCoLC)fst01047668
650 7 $aBiokatalysator$2gnd
650 7 $aEnzymkatalyse$2gnd
650 7 $aOrganische Synthese$2gnd
650 7 $aCompose s organiques$xSynthe se.$2ram
650 7 $aEnzymes.$2ram
653 0 $aOrganic compounds$aSynthesis
776 08 $iOnline version:$aHalgas , Ja n.$tBiocatalysts in organic synthesis.$dAmsterdam ; New York : Elsevier, 1992$w(OCoLC)645755663
830 0 $aStudies in organic chemistry (Elsevier Science Publishers) ;$v46.
856 41 $3Table of contents$uhttp://www.gbv.de/dms/bowker/toc/9780444986986.pdf
856 $31850-9999$uhttp://www.elsevier.com/journals$xBLDSS
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