MARC record from Internet Archive

LEADER: 05661cam 2200877Ia 4500
001 ocm30915993
003 OCoLC
005 20201014040117.0
008 940718s1994 enka b 001 0 eng
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050 4 $aQD474$b.C725 1994
082 04 $a548.3$220
082 04 $a541.22$220
084 $a35.53$2bcl
084 $aVE 7800$2rvk
084 $aVK 7150$2rvk
084 $aCHE 328f$2stub
084 $aCHE 780f$2stub
100 1 $aCram, Donald J.
245 10 $aContainer molecules and their guests /$cDonald J. Cram and Jane M. Cram.
260 $aCambridge :$bRoyal Society of Chemistry,$c©1994.
300 $axiv, 223 pages :$billustrations (some color) ;$c25 cm
336 $atext$btxt$2rdacontent
337 $aunmediated$bn$2rdamedia
338 $avolume$bnc$2rdacarrier
490 1 $aMonographs in supramolecular chemistry ;$vno. 4
504 $aIncludes bibliographical references and index.
505 2 $aContexts, conceptions, corands, and coraplexes -- Spherands, spheraplexes, and their relatives -- Chiral recognition in complexation -- Partial enzyme mimics -- Cavitands -- Vases, kites, and velcraplexes -- Carcerands and carceplexes -- Hemicarcerands and constrictive binding -- Varieties of hemicarcerands -- Reactions of complexed hosts, of incarcerated guests, and hosts protection of guests from self destruction.
520 $aThis volume covers the evolution of host-guest complexation chemistry in the minds and hands of Nobel Prize winner Donald Cram and his co-workers at UCLA, over the 25-year period from 1970-1994. It deals with the fundamental principles and objectives that govern this rapidly developing subject and illustrates the emergence of a new field of biomimetic chemistry. The book demonstrates how a number of techniques, such as molecular modeling, synthesis, crystal structure, NMR solution structure and mass spectral structure determinations can be combined to develop a new branch of organic chemistry. It discusses the chemistry of completely new families of complexes - the carceplexes, hemicarceplexes and velcarplexes - and reviews for the first time the uses of the interiors of hemicarceplexes as a new phase for carrying out chemical reactions and for protecting unstable species. Container Molecules and Their Guests illustrates how complexation and decomplexation rates are measured to provide free energies of binding, discusses new phenomena such as constrictive binding, and shows for the first time how solvophobic forces drive complexation in a variety of organic solvents, giving examples of entropy-driven complexations. It also covers catalysis through complexation and chiral recognition in catalysis, both secondary themes of this volume, and points to questions that it would not previously have been possible to ask, examining how such questions might be answered through research. Container Molecules and Their Guests will provide stimulating reading for researchers, post-graduate students and teachers involved in bio-organic chemistry, organic chemistry, materials science, and medicinal and pharmaceutical chemistry. Many will be inspired by the wonderful achievements that Cram and his team have made in this exciting branch of supramolecular chemistry.
650 0 $aComplex compounds$xSynthesis.
650 0 $aCrown ethers.
650 0 $aMolecular structure.
650 1 $aOrganic compounds.
650 2 $aMolecular Structure.
650 7 $aComplex compounds$xSynthesis.$2fast$0(OCoLC)fst00871587
650 7 $aCrown ethers.$2fast$0(OCoLC)fst00884290
650 7 $aMolecular structure.$2fast$0(OCoLC)fst01024846
650 7 $aEinschlussverbindungen$2gnd
650 7 $aWirt-Gast-Beziehung$2gnd
650 17 $aMacrocyclische verbindingen.$2gtt
650 17 $aSupramoleculaire systemen.$2gtt
650 7 $aEstrutura molecular (quimica teorica)$2larpcal
650 7 $aCompostos ciclicos.$2larpcal
650 7 $aOxicompostos e hidroxicompostos (quimica organica)$2larpcal
650 7 $aCristalografia.$2larpcal
650 7 $aComplexes donneur-accepteur d'électrons.$2ram
650 7 $aChimie supramoléculaire.$2ram
650 7 $aÉthers en couronne.$2ram
650 7 $aComposés complexes.$2ram
650 7 $aReconnaissance moléculaire.$2ram
650 7 $aStructure moléculaire.$2ram
653 1 $aMolecules$aStructure
700 1 $aCram, Jane M.
710 2 $aRoyal Society of Chemistry (Great Britain)
776 08 $iOnline version:$aCram, Donald J.$tContainer molecules and their guests.$dCambridge : Royal Society of Chemistry, ©1994$w(OCoLC)624465892
830 0 $aMonographs in supramolecular chemistry ;$vno. 4.
938 $aBaker & Taylor$bBKTY$c138.00$d138.00$i0851869726$n0002604005$sactive
938 $aBrodart$bBROD$n47580577$c$95.00
938 $aYBP Library Services$bYANK$n855940
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