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037 $a10.1039/9781847550927$bRoyal Society of Chemistry$nhttp://www.rsc.org/spr
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100 1 $aWilliams, Andrew,$d1937-
245 10 $aFree energy relationships in organic and bio-organic chemistry /$cAndrew Williams.
260 $aCambridge :$bRoyal Society of Chemistry,$c©2003.
300 $a1 online resource (xi, 297 pages) :$billustrations
336 $atext$btxt$2rdacontent
337 $acomputer$bc$2rdamedia
338 $aonline resource$bcr$2rdacarrier
504 $aIncludes bibliographical references and index.
505 0 $aFree energy relationships -- The equations -- Effective charge -- Multiple pathways to the reaction centre -- Coupling between bonds in transition structures of displacement reactions -- Anomalies, special cases and non-linearity -- Applications.
520 $aIntroducing the application of free energy correlations to elucidating the mechanisms of organic and bio-organic reactions, this book provides a new and illuminating way of approaching a potentially complex topic. The idea of how free energy correlations derive from polar substituent change is introduced, and common pitfalls encountered in the application of free energy relationships are described, along with the use of these anomalies in mechanistic studies. The concept of effective charge is described in detail, with examples of its application. Throughout, worked answers are provided for the problems posed. Databases of parameters, an extensive bibliography and comprehensive lists of further reading are also included. The text provides an invaluable source of information to senior undergraduates, postgraduates and to industrial researchers with an interest in mechanistic studies. It is the first such book in more than thirty years.
588 0 $aPrint version record.
650 0 $aLinear free energy relationship.
650 7 $aChemistry.$2bicssc
650 7 $aSCIENCE$xChemistry$xOrganic.$2bisacsh
650 7 $aScience.$2eflch
650 7 $aLinear free energy relationship.$2fast$0(OCoLC)fst00999072
650 17 $aVrije energie.$2gtt
655 0 $aElectronic books.
655 4 $aElectronic books.
776 08 $iPrint version:$aWilliams, Andrew, 1937-$tFree energy relationships in organic and bio-organic chemistry.$dCambridge : RSC, ©2003$z0854046763$w(DLC) 2005440499$w(OCoLC)52326901
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